Condensate Corrosion and Protection

Condensate recovery is one of the areas of energy source conservation consequently widely applied in companies today. Condensate still has about twenty percent of soaked steam, as well as being distilled standard water, almost totally free of dissolved debris. Therefore , their recovery offers you advantages to boilers which include reducing gasoline costs, minimizing chemical cure, conserving water, and increasing furnace efficiency. Non-contaminated condensate, which can be the product from noncontact heavy steam application, results to water vapor boiler’s system as materials water. There are two types in condensate receiving system in boilers supports the pressurized condensate program and the gravity-vented condensate program. The display steam out of high pressure condensate is saved by returning this condensate to the deaerator while the gravity-vented condensate results to the central heating boiler feed tank.

Oxygen Strike

Often people talked about due to its pureness in aspect; steam condensate requires simply no chemical cure, but is that so? Condensate is rust and can be dirtied by rusts, something that very few people are mindful. Sometimes, condensate can be marginally acidic. That is why condensate dispatch deteriorates faster than vapor piping. Much needed oxygen corrosion occurs in condensate piping seeing that pitting, which is the most destructive form of corrosion.

The reaction of oxygen assault is:

4Fe + 6H2O + 3O2 → 4Fe(OH)3
Carbonic acidity thins condensate pipes to result in grooving towards the bottom section of the pipes. The results is, if a condensate line has mostly pitting, the condensate is rich in oxygen, however if the pipe divider is thinning hair, the condensate pipe is experiencing carbonic stomach acid attack. However , where do oxygen and carbon dioxide in condensate piping originate from? Usually are not all mixed oxygen and carbon dioxide for boiler normal water arrested mechanically by the deaerator and chemically by sodium sulphite or perhaps DEHA in the boiler? Truly, there are two main reasons just for this phenomenon. Initially, when steam condenses, the flow size shrinks thereby allowing fresh air to imbed and reduce. Secondly, fresh air can also be drawn into condensate system because of condensate high heel platform sandals, leaking heat up exchangers, and vents of condensate acquiring tanks.

Acidity Corrosion

Co2 can mess up in the same way while oxygen, on the other hand, the main way to obtain carbon dioxide for steam is a breakdown of bicarbonate and carbonate alkalinity in central heating boiler water to make carbon dioxide.

Here are the response that occur:

Carbonate response: CO3 + H2O → CO2 plus 2OH
Bicarbonate reaction: 2HCO3 + heat → LASER + 2H2O
Carbon dioxide combines with water vapor, condenses on condensate to create weak carbonic acid, and lowers the pH. Condensate is so natural that even small amount of vulnerable carbonic acidity can drop the ph level to some. 5.

The response is:

In Malaysia, there was an incident in a petrochemical industry in which less than 20% of the condensate was delivered into the central heating boiler because of carbonic acid infiltration. In boiler, acidic condensate lowers ph level, erodes steel, increases break up iron, and increases the total dissolved debris (TDS) seeing that iron bicarbonate. Iron bicarbonate mixes with boiler liquid to form iron oxide and carbon dioxide, and therefore the carbon dioxide mixes with steam again. That is why a lot of people cannot preserve a high ph level in their central heating boiler despite doubling the dosage of caustic soda. This concern in condensate recovery is disadvantageous to steam boilers and must be prevented.


Protection of after-boiler condensate lines is needed. Corrosion on condensate line can be minimized by volatile amines because corrosion blockers. Volatile amines commonly used to get condensate range protection today are normalizing amines and filming amines. Neutralizing amines react with carbonic acidity and co2 to increase condensate pH to 9. One of many commonly used neutralizing amines is normally cyclohexylamine. Recording amines, however, form defending films in metal types of surface and safeguard from fresh air attack, not much different from the way magnetite film does. A good example of filming amines is octyldecylamine. Having oil-like property, filming amines layer the sheet metal surface with one-molecule dense. Filming amines have no impact on condensate ph level. Carbon dioxide and oxygen are usually more corrosive together. Accordingly, whether a system looks both oxygen and chemical attacks, various both amines is always suggested.

Besides , condensate quality monitoring should be incorporated on the daily or 7 days a week basis. Require a test of condensate to monitor golf club content, firmness, and TDS. Check for color and purchase. Any difference indicates unbalanced treatment or contamination. Condensate is not cured to remove toxic contamination, therefore , to avoid iron hydroxide infiltration; magnet filter can be applied to eliminate it from condensate. Total golf club in central heating boiler feed mineral water for medium pressure boiler should be smaller than zero. 05 ppm, and any increase may well mean iron bars hydroxide infiltration from the condensate line. To get boiler functioning below 2 0 bars, a recommended alkalinity standing is one hundred and forty to 800 ppm. In the event the alkalinity level exceeds six hundred ppm, bicarbonate and carbonate will breakdown producing carbon and drive in water vapor, as stated ahead of. However , the most effective method is to get rid of the alkaline solidity (carbonate and bicarbonate) decisivelydefinitively, determinately, once and for all, once for all by using the reverse-osmosis system as well as demineralization.

Final result

Finally, condensate is rust and detrimental to condensate piping. The danger happens when various steam designers, based on great boiler drinking water field-test outcomes, feel comfortable with their particular boiler mineral water treatments. A bit of engineers do not ever seriously consider or realize the damage that could happen to the condensate marks. This is an important negligence. When leaks immediately after leaks will be detected, it will be too late and costly fixes would be expected. It is the take care of condensate gain that makes it unneeded to replace condensate piping for quite a while.

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